Distribution function in quantal cumulant dynamics

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Distribution function in quantal cumulant dynamics.

We have derived a quantum distribution function in terms of cumulants that are expectation values of a (anti)symmetric-ordered product of position and momentum fluctuation operators. A second-order approximation leads a Gaussian distribution function, which is positive definite and has proper marginals so that the Shannon entropy can be evaluated.

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2008

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.2917799